Non-monotonic lattice expansion in zeolitic imidazolate frameworks during heating

Wessel Martinus Wilhelmus Winters; Rasmus Skov Klitgaard Madsen; Oxana Magdysyuk; Yuanzheng Yue

doi:10.1039/d4cc03841j

Non-monotonic lattice expansion in zeolitic imidazolate frameworks during heating

Wessel Martinus Wilhelmus Winters, Rasmus Skov Klitgaard Madsen, Oxana Magdysyuk, Yuanzheng Yue^*

^*Kontaktforfatter

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › peer review

Abstract

The effect of substituting linkers with two additional methyl groups for conventional benzimidazolate on the thermal expansion behaviour of ZIF-62 was investigated by high-energy in situ X-ray diffraction. Increased structural integrity was observed with the addition of methyl groups, and variable anisotropic thermal expansion was discovered in ZIF-62 and its derivative.

Originalsprog	Engelsk
Tidsskrift	Chemical Communications
Vol/bind	60
Udgave nummer	90
Sider (fra-til)	13275 - 13278
Antal sider	4
ISSN	1359-7345
DOI	https://doi.org/10.1039/d4cc03841j
Status	Udgivet - 25 okt. 2024

Emneord

Metal-organic framework (MOF)
Thermal Expansion
X-ray diffraction

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10.1039/d4cc03841j

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Citationsformater

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title = "Non-monotonic lattice expansion in zeolitic imidazolate frameworks during heating",

abstract = "The effect of substituting linkers with two additional methyl groups for conventional benzimidazolate on the thermal expansion behaviour of ZIF-62 was investigated by high-energy in situ X-ray diffraction. Increased structural integrity was observed with the addition of methyl groups, and variable anisotropic thermal expansion was discovered in ZIF-62 and its derivative.",

keywords = "Metal-organic framework (MOF), Thermal Expansion, X-ray diffraction",

author = "Winters, {Wessel Martinus Wilhelmus} and Madsen, {Rasmus Skov Klitgaard} and Oxana Magdysyuk and Yuanzheng Yue",

year = "2024",

month = oct,

day = "25",

doi = "10.1039/d4cc03841j",

language = "English",

volume = "60",

pages = "13275 -- 13278",

journal = "Chemical Communications",

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TY - JOUR

T1 - Non-monotonic lattice expansion in zeolitic imidazolate frameworks during heating

AU - Winters, Wessel Martinus Wilhelmus

AU - Madsen, Rasmus Skov Klitgaard

AU - Magdysyuk, Oxana

AU - Yue, Yuanzheng

PY - 2024/10/25

Y1 - 2024/10/25

N2 - The effect of substituting linkers with two additional methyl groups for conventional benzimidazolate on the thermal expansion behaviour of ZIF-62 was investigated by high-energy in situ X-ray diffraction. Increased structural integrity was observed with the addition of methyl groups, and variable anisotropic thermal expansion was discovered in ZIF-62 and its derivative.

AB - The effect of substituting linkers with two additional methyl groups for conventional benzimidazolate on the thermal expansion behaviour of ZIF-62 was investigated by high-energy in situ X-ray diffraction. Increased structural integrity was observed with the addition of methyl groups, and variable anisotropic thermal expansion was discovered in ZIF-62 and its derivative.

KW - Metal-organic framework (MOF)

KW - Thermal Expansion

KW - X-ray diffraction

U2 - 10.1039/d4cc03841j

DO - 10.1039/d4cc03841j

M3 - Journal article

SN - 1359-7345

VL - 60

SP - 13275

EP - 13278

JO - Chemical Communications

JF - Chemical Communications

IS - 90

ER -

Non-monotonic lattice expansion in zeolitic imidazolate frameworks during heating

Abstract

Emneord

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