Quantum spill-out in few-nanometer metal gaps: Effect on gap plasmons and reflectance from ultrasharp groove arrays

Enok Johannes Haahr Skjølstrup, Thomas Søndergaard, Thomas Garm Pedersen

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningpeer review

9 Citationer (Scopus)
273 Downloads (Pure)

Abstrakt

Plasmons in ultranarrow metal gaps are highly sensitive to the electron density profile at the metal surfaces. Using a quantum mechanical approach and assuming local response, we study the effects of electron spill-out on gap plasmons and reflectance from ultrasharp metal grooves.We demonstrate that the mode index of ultranarrow gap plasmons converges to the bulk refractive index in the limit of vanishing gap and, thereby, rectify the unphysical divergence found in classical models. Surprisingly, spill-out also significantly increases the plasmonic absorption for few-nanometer gaps and lowers the reflectance from arrays of ultrasharp metal grooves. These findings are explained in terms of enhanced gap plasmon absorption taking place inside the gap 1–2 °A from the walls and delocalization near the groove bottom. Reflectance calculations taking spill-out into account are shown to be in
much better agreement with measurements compared with classical models.
OriginalsprogEngelsk
Artikelnummer115429
TidsskriftPhysical Review B
Vol/bind97
Udgave nummer11
Sider (fra-til)1-9
Antal sider9
ISSN2469-9950
DOI
StatusUdgivet - 19 mar. 2018

Emneord

  • Gap plasmons
  • Mode index
  • Electron spill-out
  • Density functional theory
  • Ultrasharp grooves
  • Metal optics

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