Abstract
The effect of substituting linkers with electron-donating moieties for part of the conventional ones on the melting and glass transition behaviours of ZIF-62 was investigated by calorimetry and X-ray diffraction. Specifically, substituting 5,6-dimethylbenzimidazole for benzimidazole in ZIF-62 increases both Tm and Tg. The structural origin of this effect was explained.
Originalsprog | Engelsk |
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Tidsskrift | Chemical Communications |
Vol/bind | 58 |
Udgave nummer | 6 |
Sider (fra-til) | 823–826 |
Antal sider | 4 |
ISSN | 1359-7345 |
DOI | |
Status | Udgivet - 2022 |