Structural Evolution in a Melt-Quenched Zeolitic Imidazolate Framework Glass during Heat-treatment

Jiayan Zhang, L. Longley, Hao Liu, C.W. Ashling, P.A. Chater, K.A. Beyer, K.W. Chapman, H.Z. Tao, D.A. Keen, T.D. Bennett, Yuanzheng Yue

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningpeer review

4 Citationer (Scopus)

Abstrakt

A pronounced enthalpy release occurs around 1.38T g in the prototypical metal-organic framework glass formed from ZIF-4 [Zn(C 3 H 3 N 2 ) 2 ], but there is no sign for any crystallization (i.e., long-range ordering) taking place. The enthalpy release peak is attributed to pore collapse and structural densification.

OriginalsprogEngelsk
Artikelnummer17
TidsskriftChemical Communications
Vol/bind55
Udgave nummer17
Sider (fra-til)2521-2524
Antal sider4
ISSN1359-7345
DOI
StatusUdgivet - 4 feb. 2019

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  • Citationsformater

    Zhang, J., Longley, L., Liu, H., Ashling, C. W., Chater, P. A., Beyer, K. A., Chapman, K. W., Tao, H. Z., Keen, D. A., Bennett, T. D., & Yue, Y. (2019). Structural Evolution in a Melt-Quenched Zeolitic Imidazolate Framework Glass during Heat-treatment. Chemical Communications, 55(17), 2521-2524. [17]. https://doi.org/10.1039/c8cc09574d