Abstract
Governing equations are developed for equilibrium swelling of a cationic polyelectrolyte gel in aqueous solutions with various pH and molar fractions of a monovalent salt. Material constants are determined by fitting observations on several homo- and copolymer gels in two types of tests: when swelling is conducted in water baths with varied pH and a fixed molar fraction of salt, and when experiments are performed in water baths with a fixed pH and varied concentration of salt. Phenomenological relations are suggested for the effect of total volume fraction of monomers in a pre-gel solution, molar fraction of ionic monomers, and molar fraction of cross-linker on adjustable parameters in the model.
Originalsprog | Engelsk |
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Tidsskrift | European Polymer Journal |
Vol/bind | 79 |
Sider (fra-til) | 23-35 |
Antal sider | 13 |
ISSN | 0014-3057 |
DOI | |
Status | Udgivet - 1 jun. 2016 |