Abstrakt
The present study demonstrates the utilization of in situ generated supramolecular ensemble of aggregates of pentacenequinone derivative 3 and cadmium nanoparticles (CdNPs) as an efficient catalytic system for (1) oxidant free, controlled and selective monofunctionalization and hetero/homo difunctionalization of 1,4-benzoquinone by C−H activation at room temperature (2) photocatalytic C−H functionalization of azoles with bromoarenes and (3) C−H functionalization of benzothiazole with simple arenes in ecofriendly conditions under visible light irradiations. Thus, a range of C2-arylated quinone and azole derivatives are synthesized from simple substrates using this newly developed catalytic/photocatalytic system under economic and ecofriendly conditions.
Originalsprog | Engelsk |
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Tidsskrift | ChemistrySelect |
Vol/bind | 2 |
Udgave nummer | 2 |
Sider (fra-til) | 680-687 |
Antal sider | 8 |
ISSN | 2365-6549 |
DOI | |
Status | Udgivet - 1 jan. 2017 |
Udgivet eksternt | Ja |