TY - JOUR
T1 - Thermo-mechanical behavior of elastomers with dynamic covalent bonds
AU - Drozdov, A. D.
AU - deClaville Christiansen, Jesper
PY - 2020/2
Y1 - 2020/2
N2 - Natural and synthetic rubbers (networks of polymer chains connected by irreversible chemical cross-links) cannot be repaired after damage, while discarded rubbers cannot be economically recycled and reprocessed. To avoid this shortcoming, a number of elastomers with dynamic covalent bonds have recently been synthesized that demonstrate recyclability, malleability and capability of autonomous self-healing due to thermally triggered bond-exchange reactions. A constitutive model is developed for the thermo-viscoelastic and thermo-viscoplastic responses of elastomers whose chains are bridged by adaptive bonds with the associative mechanism of rearrangement. Material parameters in the governing equations are determined by fitting observations in tensile tests, cyclic tests, relaxation tests and creep tests in a wide range of temperatures on covalently cross-linked rubber, thermoplastic elastomer, several elastomers and elastomer nanocomposites with dynamic covalent bonds, and epoxy vitrimers. Characteristic features are discussed of the thermo-mechanical behavior of elastomers with dynamic bonds and structure–property relations are established for these materials.
AB - Natural and synthetic rubbers (networks of polymer chains connected by irreversible chemical cross-links) cannot be repaired after damage, while discarded rubbers cannot be economically recycled and reprocessed. To avoid this shortcoming, a number of elastomers with dynamic covalent bonds have recently been synthesized that demonstrate recyclability, malleability and capability of autonomous self-healing due to thermally triggered bond-exchange reactions. A constitutive model is developed for the thermo-viscoelastic and thermo-viscoplastic responses of elastomers whose chains are bridged by adaptive bonds with the associative mechanism of rearrangement. Material parameters in the governing equations are determined by fitting observations in tensile tests, cyclic tests, relaxation tests and creep tests in a wide range of temperatures on covalently cross-linked rubber, thermoplastic elastomer, several elastomers and elastomer nanocomposites with dynamic covalent bonds, and epoxy vitrimers. Characteristic features are discussed of the thermo-mechanical behavior of elastomers with dynamic bonds and structure–property relations are established for these materials.
KW - Constitutive modeling
KW - Dynamic covalent bond
KW - Elastomer
KW - Nanocomposite
KW - Thermo-mechanical response
UR - http://www.scopus.com/inward/record.url?scp=85076460998&partnerID=8YFLogxK
U2 - 10.1016/j.ijengsci.2019.103200
DO - 10.1016/j.ijengsci.2019.103200
M3 - Journal article
SN - 0020-7225
VL - 147
JO - International Journal of Engineering Science
JF - International Journal of Engineering Science
M1 - 103200
ER -