TY - JOUR
T1 - BaAl2Si2O8 polymorphs and a novel reversible transition of BaAlF5 in supercooled oxyfluoride aluminosilicate liquids
AU - Hu, Y.B.
AU - Shao, X.Y.
AU - Wang, Z.Y.
AU - Xu, X.L.
AU - Han, X.J.
AU - Tao, H.Z.
AU - Yue, Yuanzheng
PY - 2021/11
Y1 - 2021/11
N2 - Crystallization plays a critical role in realizing the functionalization of glass materials. However, it is imperative to understand the microscopic mechanism of both the formation and the phase transitions of nanocrystals during heat processes. Here, in the as-prepared SiO2-Al2O3-BaF2-Na2O glass, we studied the polymorphic phase transition of BaAl2Si2O8 during heating-cooling circles, and a novel reversible transformation is found by serendipity. Using differential scanning calorimetry (DSC), we observed an endothermic event around 1047 K during heating at 20 K/min to 1173 K, and an exotherm event at 1024 K during the subsequent cooling. Based on the X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM), the reversible process was attributed to the transition between two morphs of BaAlF5 nano-crystal. Na2O introduced in the studied glass system promotes the transformation between hexacelsian (Hexagonal) and celsian (Monoclinic). The results also show the formation of different types of crystals, such as, BaF2, Na5Al3F14 and BaAlF5 etc.
AB - Crystallization plays a critical role in realizing the functionalization of glass materials. However, it is imperative to understand the microscopic mechanism of both the formation and the phase transitions of nanocrystals during heat processes. Here, in the as-prepared SiO2-Al2O3-BaF2-Na2O glass, we studied the polymorphic phase transition of BaAl2Si2O8 during heating-cooling circles, and a novel reversible transformation is found by serendipity. Using differential scanning calorimetry (DSC), we observed an endothermic event around 1047 K during heating at 20 K/min to 1173 K, and an exotherm event at 1024 K during the subsequent cooling. Based on the X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM), the reversible process was attributed to the transition between two morphs of BaAlF5 nano-crystal. Na2O introduced in the studied glass system promotes the transformation between hexacelsian (Hexagonal) and celsian (Monoclinic). The results also show the formation of different types of crystals, such as, BaF2, Na5Al3F14 and BaAlF5 etc.
KW - BaAl Si O
KW - BaAlF
KW - Oxyfluoride aluminosilicate glass-ceramic
KW - Polymorphic phase transition
KW - Reversible transformation
UR - http://www.scopus.com/inward/record.url?scp=85110281070&partnerID=8YFLogxK
U2 - 10.1016/j.jeurceramsoc.2021.07.021
DO - 10.1016/j.jeurceramsoc.2021.07.021
M3 - Journal article
SN - 0955-2219
VL - 41
SP - 7282
EP - 7287
JO - Journal of the European Ceramic Society
JF - Journal of the European Ceramic Society
IS - 14
ER -