Grey-box Modeling of Reversible Solid Oxide Cell Stack’s Electrical Dynamics Based on Electrochemical Impedance Spectroscopy

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Abstract

This paper aims to design a lumped-capacity model
of a reversible solid oxide cell stack for hydrogen electrolysis.
The lumped-capacity model needs to have an adequate representation
of the electrical dynamics over a wide operating
range and a model structure suitable for the design of a physical
emulator. The grey-box model is based on data obtained by electrochemical
impedance spectroscopy conducted on a commercial
solid oxide cell stack for four different gas compositions at six
aging stages. In addition, a comparison of the experimental and
simulated voltage response of the reversible solid oxide cell stack
in cyclic reversible operation mode was conducted at different
aging levels of the stack.
Original languageEnglish
Title of host publication2023 IEEE Conference on Control Technology and Applications (CCTA)
PublisherIEEE Press
Publication date2023
Publication statusPublished - 2023
SeriesProceedings of the IEEE Conference on Control Technology and Applications (CCTA)

Keywords

  • System Identification
  • Grey-Box Modeling
  • Electromechanical Impedance Spectroscopy
  • Electrolysis

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