Hot-Spot Engineering in 3D Multi-Branched Nanostructures: Ultrasensitive Substrates for Surface-Enhanced Raman Spectroscopy

Manohar Chirumamilla, Anisha Chirumamilla, Alexander Roberts, Remo Proietti Zaccaria, Francesco De Angelis, Peter Kjær Kristensen, Roman Krahe, Sergey I. Bozhevolnyi, Kjeld Pedersen, Andrea Toma

Research output: Contribution to journalJournal articleResearchpeer-review

36 Citations (Scopus)

Abstract

The detection of probe molecules at ultralow concentrations, even at the
single-molecule level, can be addressed with the breakthrough concept of
plasmonic hot-spot engineering. In view of that, the fabrication of nanostructures
endowed with sub-10 nm gaps and extremely large near-field enhancement
has gained increasing attention, becoming a key-condition for improved
sensitivity. The present work demonstrates a new perspective in ultrasensitive
detection by engineering every individual plasmonic nanostructure with a
giant electric field confinement and superior hot-spot densities, thus eliminating
the need for extremely narrow interparticle separations.
Original languageEnglish
Article number1600836
JournalAdvanced Optical Materials
Volume5
Issue number4
Number of pages7
ISSN2195-1071
DOIs
Publication statusPublished - 2017

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