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Abstract
Improving the fracture resistance of oxide glasses through adjustment of the chemical composition remains a challenging task, although composition-mechanical property relations have been established for simple model systems. The glass mechanical properties are, among other methods, conventionally tested using instrumented indentation, which is a fast and convenient technique that mimics the real-life damage for certain applications, although interpretation can be challenging due to the complex stress fields that develop under the indenter. Early indentation experiments have shown that oxide glasses exhibit pronounced tendency to densify under compressive load compared to metals and ceramics. After decades of investigations, it is now known that the extent of densification is strongly dependent on the glass’ chemical composition and in turn its atomic packing density and Poisson's ratio. Spectroscopic techniques have shed light on the mechanism of densification, which include changes in the bond angle distributions as well as an increase in the coordination number of the network-forming cations. Knowledge of such details is crucial for understanding the link between chemical composition and resistance to cracking in oxide glasses, since densification is an efficient way to dissipate the elastic energy applied to the material during indentation. Here, we review the experimental work on identification and quantification of indentation deformation in glasses, as well as on probing the accompanying structural changes in the glassy network. We also include the conclusions drawn from computer simulation studies, which can provide atomistic details of the indentation deformation mechanisms. Finally, we discuss the link between the mechanism of deformation and the crack resistance.
Original language | English |
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Article number | 100007 |
Journal | Journal of Non-Crystalline Solids: X |
Volume | 1 |
Number of pages | 20 |
ISSN | 2590-1591 |
DOIs | |
Publication status | Published - 1 Mar 2019 |
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Dive into the research topics of 'Indentation deformation in oxide glasses: Quantification, structural changes, and relation to cracking'. Together they form a unique fingerprint.Projects
- 1 Finished
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Glass Mechanical Properties: Structural Origins and Engineering
Smedskjær, M. M. (PI), Yue, Y. (PI), Somers, M. A. J. (PI), Januchta, K. (Project Participant) & To, T. (Project Participant)
01/10/2016 → 28/02/2021
Project: Research
Research output
- 85 Citations
- 1 Comment/debate
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Erratum to Indentation deformation in oxide glasses: Quantification, structural changes, and relation to cracking [Journal of Non crystalline solids:X 1C (2019) 100007] (Journal of Non-Crystalline Solids: X (2019) 1, (S2590159118300074), (10.1016/j.nocx.2018.100007))
Januchta, K. & Smedskjaer, M. M., Jun 2023, In: Journal of Non-Crystalline Solids: X. 18, 100144.Research output: Contribution to journal › Comment/debate › Research › peer-review
Open Access