Over 14% efficiency all-polymer solar cells enabled by a low bandgap polymer acceptor with low energy loss and efficient charge separation

Qunping Fan; Qiaoshi An; Yuanbao Lin; Yuxin Xia; Qian Li; Ming Zhang; Wenyan Su; Wenhong Peng; Chunfeng Zhang; Feng Liu; Lintao Hou; Weiguo Zhu; Donghong Yu; Min Xiao; Ellen Moons; Fujun Zhang; Thomas D. Anthopoulos; Olle Inganäs; Ergang Wang

doi:10.1039/d0ee01828g

Over 14% efficiency all-polymer solar cells enabled by a low bandgap polymer acceptor with low energy loss and efficient charge separation

Qunping Fan, Qiaoshi An, Yuanbao Lin, Yuxin Xia, Qian Li, Ming Zhang, Wenyan Su, Wenhong Peng, Chunfeng Zhang, Feng Liu, Lintao Hou, Weiguo Zhu, Donghong Yu, Min Xiao, Ellen Moons, Fujun Zhang, Thomas D. Anthopoulos, Olle Inganäs, Ergang Wang^*

^*Corresponding author for this work

Research output: Contribution to journal › Journal article › Research › peer-review

165 Citations (Scopus)

21 Downloads (Pure)

Abstract

Obtaining both high open-circuit voltage (Voc) and short-circuit current density (Jsc) has been a major challenge for efficient all-polymer solar cells (all-PSCs). Herein, we developed a polymer acceptor PF5-Y5 with excellent optical absorption capability (onset extending to ∼880 nm and maximum absorption coefficient exceeding 105 cm-1 in a film), high electron mobility (3.18 × 10-3 cm2 V-1 s-1) and high LUMO level (-3.84 eV) to address such a challenge. As a result, the PBDB-T:PF5-Y5-based all-PSCs achieved a high power conversion efficiency of up to 14.45% with both a high Voc (0.946 V) and a high Jsc (20.65 mA cm-2), due to the high and broad absorption coverage, small energy loss (0.57 eV) and efficient charge separation and transport in the device, which are among the best values in the all-PSC field. In addition, the all-PSC shows a ∼15% improvement in PCE compared to its counterpart small molecule acceptor (Y5)-based device. Our results suggest that PF5-Y5 is a very promising polymer acceptor candidate for applications in efficient all-PSCs. This journal is

Original language	English
Journal	Energy and Environmental Science
Volume	13
Issue number	12
Pages (from-to)	5017-5027
Number of pages	11
ISSN	1754-5692
DOIs	https://doi.org/10.1039/d0ee01828g
Publication status	Published - Dec 2020

Bibliographical note

Funding Information:
We thank the Swedish Research Council (2015-04853, 2016-06146, 2019-04683), the Swedish Research Council Formas, and the Wallenberg Foundation (2017.0186, 2016.0059) for financial support. D. Y. is thankful for the financial support from Innovation fund Denmark (INKA project) and Sino-Danish Centre for Education and Research (SDC). Y. L. and T. D. A. acknowledge support from the King Abdullah University of Science and Technology (KAUST) and Office of Sponsored Research (OSR) under Award No: OSR-2018-CARF/CCF-3079. W. S. is thankful for the project funded by Jinan University Postdoctoral Science Foundation, China Postdoctoral Science Foundation (2020M673054), and National Natural Science Foundation of China (22005121). Q. A. is thankful for the project funded by the National Natural Science Foundation of China (61805009).

Publisher Copyright:
© The Royal Society of Chemistry.

Copyright:
Copyright 2021 Elsevier B.V., All rights reserved.

Access to Document

10.1039/d0ee01828gLicence: CC BY 3.0

Open Access versionFinal published version, 4.04 MBLicence: CC BY 3.0

AUB Link

Search for the material in Aalborg University Library's search engine

Cite this

Fan, Q., An, Q., Lin, Y., Xia, Y., Li, Q., Zhang, M., Su, W., Peng, W., Zhang, C., Liu, F., Hou, L., Zhu, W., Yu, D., Xiao, M., Moons, E., Zhang, F., Anthopoulos, T. D., Inganäs, O., & Wang, E. (2020). Over 14% efficiency all-polymer solar cells enabled by a low bandgap polymer acceptor with low energy loss and efficient charge separation. Energy and Environmental Science, 13(12), 5017-5027. https://doi.org/10.1039/d0ee01828g

@article{b43c5f0597cb4620ae4b5c849b6dfc6b,

title = "Over 14% efficiency all-polymer solar cells enabled by a low bandgap polymer acceptor with low energy loss and efficient charge separation",

abstract = "Obtaining both high open-circuit voltage (Voc) and short-circuit current density (Jsc) has been a major challenge for efficient all-polymer solar cells (all-PSCs). Herein, we developed a polymer acceptor PF5-Y5 with excellent optical absorption capability (onset extending to ∼880 nm and maximum absorption coefficient exceeding 105 cm-1 in a film), high electron mobility (3.18 × 10-3 cm2 V-1 s-1) and high LUMO level (-3.84 eV) to address such a challenge. As a result, the PBDB-T:PF5-Y5-based all-PSCs achieved a high power conversion efficiency of up to 14.45% with both a high Voc (0.946 V) and a high Jsc (20.65 mA cm-2), due to the high and broad absorption coverage, small energy loss (0.57 eV) and efficient charge separation and transport in the device, which are among the best values in the all-PSC field. In addition, the all-PSC shows a ∼15% improvement in PCE compared to its counterpart small molecule acceptor (Y5)-based device. Our results suggest that PF5-Y5 is a very promising polymer acceptor candidate for applications in efficient all-PSCs. This journal is ",

author = "Qunping Fan and Qiaoshi An and Yuanbao Lin and Yuxin Xia and Qian Li and Ming Zhang and Wenyan Su and Wenhong Peng and Chunfeng Zhang and Feng Liu and Lintao Hou and Weiguo Zhu and Donghong Yu and Min Xiao and Ellen Moons and Fujun Zhang and Anthopoulos, {Thomas D.} and Olle Ingan{\"a}s and Ergang Wang",

note = "Funding Information: We thank the Swedish Research Council (2015-04853, 2016-06146, 2019-04683), the Swedish Research Council Formas, and the Wallenberg Foundation (2017.0186, 2016.0059) for financial support. D. Y. is thankful for the financial support from Innovation fund Denmark (INKA project) and Sino-Danish Centre for Education and Research (SDC). Y. L. and T. D. A. acknowledge support from the King Abdullah University of Science and Technology (KAUST) and Office of Sponsored Research (OSR) under Award No: OSR-2018-CARF/CCF-3079. W. S. is thankful for the project funded by Jinan University Postdoctoral Science Foundation, China Postdoctoral Science Foundation (2020M673054), and National Natural Science Foundation of China (22005121). Q. A. is thankful for the project funded by the National Natural Science Foundation of China (61805009). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",

year = "2020",

month = dec,

doi = "10.1039/d0ee01828g",

language = "English",

volume = "13",

pages = "5017--5027",

journal = "Energy and Environmental Science",

issn = "1754-5692",

publisher = "Royal Society of Chemistry",

number = "12",

}

Fan, Q, An, Q, Lin, Y, Xia, Y, Li, Q, Zhang, M, Su, W, Peng, W, Zhang, C, Liu, F, Hou, L, Zhu, W, Yu, D, Xiao, M, Moons, E, Zhang, F, Anthopoulos, TD, Inganäs, O & Wang, E 2020, 'Over 14% efficiency all-polymer solar cells enabled by a low bandgap polymer acceptor with low energy loss and efficient charge separation', Energy and Environmental Science, vol. 13, no. 12, pp. 5017-5027. https://doi.org/10.1039/d0ee01828g

TY - JOUR

T1 - Over 14% efficiency all-polymer solar cells enabled by a low bandgap polymer acceptor with low energy loss and efficient charge separation

AU - Fan, Qunping

AU - An, Qiaoshi

AU - Lin, Yuanbao

AU - Xia, Yuxin

AU - Li, Qian

AU - Zhang, Ming

AU - Su, Wenyan

AU - Peng, Wenhong

AU - Zhang, Chunfeng

AU - Liu, Feng

AU - Hou, Lintao

AU - Zhu, Weiguo

AU - Yu, Donghong

AU - Xiao, Min

AU - Moons, Ellen

AU - Zhang, Fujun

AU - Anthopoulos, Thomas D.

AU - Inganäs, Olle

AU - Wang, Ergang

N1 - Funding Information: We thank the Swedish Research Council (2015-04853, 2016-06146, 2019-04683), the Swedish Research Council Formas, and the Wallenberg Foundation (2017.0186, 2016.0059) for financial support. D. Y. is thankful for the financial support from Innovation fund Denmark (INKA project) and Sino-Danish Centre for Education and Research (SDC). Y. L. and T. D. A. acknowledge support from the King Abdullah University of Science and Technology (KAUST) and Office of Sponsored Research (OSR) under Award No: OSR-2018-CARF/CCF-3079. W. S. is thankful for the project funded by Jinan University Postdoctoral Science Foundation, China Postdoctoral Science Foundation (2020M673054), and National Natural Science Foundation of China (22005121). Q. A. is thankful for the project funded by the National Natural Science Foundation of China (61805009). Publisher Copyright: © The Royal Society of Chemistry. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2020/12

Y1 - 2020/12

N2 - Obtaining both high open-circuit voltage (Voc) and short-circuit current density (Jsc) has been a major challenge for efficient all-polymer solar cells (all-PSCs). Herein, we developed a polymer acceptor PF5-Y5 with excellent optical absorption capability (onset extending to ∼880 nm and maximum absorption coefficient exceeding 105 cm-1 in a film), high electron mobility (3.18 × 10-3 cm2 V-1 s-1) and high LUMO level (-3.84 eV) to address such a challenge. As a result, the PBDB-T:PF5-Y5-based all-PSCs achieved a high power conversion efficiency of up to 14.45% with both a high Voc (0.946 V) and a high Jsc (20.65 mA cm-2), due to the high and broad absorption coverage, small energy loss (0.57 eV) and efficient charge separation and transport in the device, which are among the best values in the all-PSC field. In addition, the all-PSC shows a ∼15% improvement in PCE compared to its counterpart small molecule acceptor (Y5)-based device. Our results suggest that PF5-Y5 is a very promising polymer acceptor candidate for applications in efficient all-PSCs. This journal is

AB - Obtaining both high open-circuit voltage (Voc) and short-circuit current density (Jsc) has been a major challenge for efficient all-polymer solar cells (all-PSCs). Herein, we developed a polymer acceptor PF5-Y5 with excellent optical absorption capability (onset extending to ∼880 nm and maximum absorption coefficient exceeding 105 cm-1 in a film), high electron mobility (3.18 × 10-3 cm2 V-1 s-1) and high LUMO level (-3.84 eV) to address such a challenge. As a result, the PBDB-T:PF5-Y5-based all-PSCs achieved a high power conversion efficiency of up to 14.45% with both a high Voc (0.946 V) and a high Jsc (20.65 mA cm-2), due to the high and broad absorption coverage, small energy loss (0.57 eV) and efficient charge separation and transport in the device, which are among the best values in the all-PSC field. In addition, the all-PSC shows a ∼15% improvement in PCE compared to its counterpart small molecule acceptor (Y5)-based device. Our results suggest that PF5-Y5 is a very promising polymer acceptor candidate for applications in efficient all-PSCs. This journal is

UR - http://www.scopus.com/inward/record.url?scp=85098322481&partnerID=8YFLogxK

U2 - 10.1039/d0ee01828g

DO - 10.1039/d0ee01828g

M3 - Journal article

AN - SCOPUS:85098322481

SN - 1754-5692

VL - 13

SP - 5017

EP - 5027

JO - Energy and Environmental Science

JF - Energy and Environmental Science

IS - 12

ER -

Over 14% efficiency all-polymer solar cells enabled by a low bandgap polymer acceptor with low energy loss and efficient charge separation

Abstract

Bibliographical note

Access to Document

AUB Link

Other files and links

Fingerprint

Cite this