Sensitivity of the glass transition and melting in a metal-organic framework to ligand chemistry

Rasmus Skov Klitgaard Madsen; S Sarkar; B.B. Iversen; Yuanzheng Yue

doi:10.1039/d1cc03541j

Sensitivity of the glass transition and melting in a metal-organic framework to ligand chemistry

Rasmus Skov Klitgaard Madsen, S Sarkar, B.B. Iversen, Yuanzheng Yue

Research output: Contribution to journal › Journal article › Research › peer-review

7 Citations (Scopus)

Abstract

The effect of substituting linkers with electron-donating moieties for part of the conventional ones on the melting and glass transition behaviours of ZIF-62 was investigated by calorimetry and X-ray diffraction. Specifically, substituting 5,6-dimethylbenzimidazole for benzimidazole in ZIF-62 increases both T_m and T_g. The structural origin of this effect was explained.

Original language	English
Journal	Chemical Communications
Volume	58
Issue number	6
Pages (from-to)	823–826
Number of pages	4
ISSN	1359-7345
DOIs	https://doi.org/10.1039/d1cc03541j
Publication status	Published - 2022

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title = "Sensitivity of the glass transition and melting in a metal-organic framework to ligand chemistry",

abstract = "The effect of substituting linkers with electron-donating moieties for part of the conventional ones on the melting and glass transition behaviours of ZIF-62 was investigated by calorimetry and X-ray diffraction. Specifically, substituting 5,6-dimethylbenzimidazole for benzimidazole in ZIF-62 increases both Tm and Tg. The structural origin of this effect was explained.",

author = "Madsen, {Rasmus Skov Klitgaard} and S Sarkar and B.B. Iversen and Yuanzheng Yue",

year = "2022",

doi = "10.1039/d1cc03541j",

language = "English",

volume = "58",

pages = "823–826",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Sensitivity of the glass transition and melting in a metal-organic framework to ligand chemistry

AU - Madsen, Rasmus Skov Klitgaard

AU - Sarkar, S

AU - Iversen, B.B.

AU - Yue, Yuanzheng

PY - 2022

Y1 - 2022

N2 - The effect of substituting linkers with electron-donating moieties for part of the conventional ones on the melting and glass transition behaviours of ZIF-62 was investigated by calorimetry and X-ray diffraction. Specifically, substituting 5,6-dimethylbenzimidazole for benzimidazole in ZIF-62 increases both Tm and Tg. The structural origin of this effect was explained.

AB - The effect of substituting linkers with electron-donating moieties for part of the conventional ones on the melting and glass transition behaviours of ZIF-62 was investigated by calorimetry and X-ray diffraction. Specifically, substituting 5,6-dimethylbenzimidazole for benzimidazole in ZIF-62 increases both Tm and Tg. The structural origin of this effect was explained.

UR - http://www.scopus.com/inward/record.url?scp=85123581143&partnerID=8YFLogxK

U2 - 10.1039/d1cc03541j

DO - 10.1039/d1cc03541j

M3 - Journal article

SN - 1359-7345

VL - 58

SP - 823

EP - 826

JO - Chemical Communications

JF - Chemical Communications

IS - 6

ER -

Sensitivity of the glass transition and melting in a metal-organic framework to ligand chemistry

Abstract

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