Abstract
Structural heterogeneity plays a crucial role in determining functionality of glasses. In this work we have found that the sub-Tg enthalpy relaxation pattern in a hyperquenched glass is highly sensitive to structural heterogeneity. As a consequence, the former can be used as an effective approach to detect and quantify the structural heterogeneity in glass-forming liquids. However, the chemical nature of structural heterogeneity should be revealed by other means such as high resolution microscopic and spectroscopic methods. To study the impact of the structural heterogeneity on the sub-Tg relaxation we chose the glass compositions with very different glass stabilities to crystallization. By using hyperquenching-annealing-calorimetry approach, we have observed that the pattern of calorimetric response below Tg dramatically varies with glass composition. The variations are attributed to different chemical features and degrees of structural heterogeneity in glass-forming liquids. This finding contributes to the microscopic origin of both the primary and secondary relaxation in terms of structural heterogeneity. Finally the results provide insights into the relation between structural heterogeneity and nucleation in glass.
Original language | English |
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Publication date | 2013 |
Number of pages | 1 |
Publication status | Published - 2013 |
Event | 10th Pacific Rim Conference on Ceramic and Glass Technology - San Diego, United States Duration: 2 Jun 2013 → 7 Jun 2013 |
Conference
Conference | 10th Pacific Rim Conference on Ceramic and Glass Technology |
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Country/Territory | United States |
City | San Diego |
Period | 02/06/2013 → 07/06/2013 |