The coadsorption of hydrogen and carbon dioxide versus adsorption of formic acid on Cs-dosed Cu(110)

P. J. Godowski, Jens Onsgaard, S. V. Hoffmann, Susanne Quist Sckerl

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    Abstract

    Investigations of the CO2/H coadsorption system on Cs-modified Cu(1 1 0), using surface sensitive spectroscopies (photoelectron spectroscopy, LEED, work function changes-Delta Phi), are presented. The valence band spectra, obtained by photoelectron spectroscopy excited by synchrotron radiation, represent "fingerprints" of adsorbed species which were used for determination of their chemical identity. The photoelectron spectra of formic acid and formate are discussed and compared with the results from molecules formed during surface reactions. (C) 2001 Elsevier Science Ltd. All rights reserved.
    Original languageEnglish
    JournalVacuum
    Volume63
    Issue number1-2
    Pages (from-to)257-266
    Number of pages10
    ISSN0042-207X
    Publication statusPublished - 2001

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