TY - JOUR
T1 - Three-level pore structure hydrogels for solar vapor generation
AU - Chen, Yang
AU - Qiu, Hongsen
AU - Li, Xianfeng
AU - Tong, Qikun
AU - Jensen, Martin
AU - Li, Qing
AU - Wang, Ning
PY - 2022
Y1 - 2022
N2 - Photothermal evaporation materials have drawn attention owing to their high solar energy utilization. In this work, a series of three-level pore structure hydrogels (TLPSHs) consisting of polyvinyl alcohol (PVA), graphene oxide (GO) or reduced graphene oxide (rGO) are prepared. The hydrogel with PVA crosslinked with rGO shows the most promising properties mainly owing to its three-level pore structure being a combination of nanosized pores for low enthalpy water evaporation and a broad distribution of micronsized pores facilitating water transport into said nanosized pores. When varying the content of rGO/PVA between 5 and 15 wt%, the 10 wt% loading gives the highest water evaporation rate and energy conversion efficient owing to its microstructure combining intra water hydrogen disruption and water transport. The TLPSHs with 88 % porosity has more than 97 % sunlight absorption throughout the UV–Vis-NIR spectrum and stable evaporation rate (1.65 kg m-2h−1) under 1 sun irradiation. The hydrogel rejects salt by having a higher temperature than the surrounding seawater which causes salt to precipitate in the water rather than on the hydrogel evaporator when the saturation limit is reached. Lastly, the scalability and real life applicability is demonstrated through outdoor experiments on seawater.
AB - Photothermal evaporation materials have drawn attention owing to their high solar energy utilization. In this work, a series of three-level pore structure hydrogels (TLPSHs) consisting of polyvinyl alcohol (PVA), graphene oxide (GO) or reduced graphene oxide (rGO) are prepared. The hydrogel with PVA crosslinked with rGO shows the most promising properties mainly owing to its three-level pore structure being a combination of nanosized pores for low enthalpy water evaporation and a broad distribution of micronsized pores facilitating water transport into said nanosized pores. When varying the content of rGO/PVA between 5 and 15 wt%, the 10 wt% loading gives the highest water evaporation rate and energy conversion efficient owing to its microstructure combining intra water hydrogen disruption and water transport. The TLPSHs with 88 % porosity has more than 97 % sunlight absorption throughout the UV–Vis-NIR spectrum and stable evaporation rate (1.65 kg m-2h−1) under 1 sun irradiation. The hydrogel rejects salt by having a higher temperature than the surrounding seawater which causes salt to precipitate in the water rather than on the hydrogel evaporator when the saturation limit is reached. Lastly, the scalability and real life applicability is demonstrated through outdoor experiments on seawater.
KW - Micro-environment
KW - Solar vapor generation
KW - Three-level pore structure
KW - Ultrahigh porosity
KW - Water transport
UR - http://www.scopus.com/inward/record.url?scp=85122942876&partnerID=8YFLogxK
U2 - 10.1016/j.apsusc.2022.152483
DO - 10.1016/j.apsusc.2022.152483
M3 - Journal article
SN - 0169-4332
VL - 582
JO - Applied Surface Science
JF - Applied Surface Science
M1 - 152483
ER -