Effect of cross-linking of high-density polyethylene. I. On spherulitic structures

Research output: Contribution to journalJournal articleResearchpeer-review

3 Citations (Scopus)
Original languageEnglish
JournalJournal of macromolecular science. Physics
Volume40
Issue number3-4
Pages (from-to)335-341
Number of pages7
ISSN0022-2348
Publication statusPublished - 2001

Bibliographical note

Abstract: Crystallization behavior and spherulitic structure of linear high-density polyethylene (HDPE), after being irradiated in its molten state by gamma -rays, was investigated by small-angle laser scattering (SALS) and differential scanning calorimetry (DSC). Significant changes in the crystallization of HDPE during cooling in air before and after being irradiated in the melt were observed. A critical minimum average molar mass between cross-links (200 carbon-carbon bonds) for spherulite formation in such an irradiated HDPE network was obtained.

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