Temperature dependence of poly(lactic acid) mechanical properties

The mechanical properties of polymers are not only determined by their structures, but also related to the
temperature field in which they are located. The yield behaviors, Young's modulus and structures of
injection-molded poly(lactic acid) (PLA) samples after annealing at different temperatures were measured
during stretching within 30–150 oC. The in situ photographs were recorded with a camera to observe
deformation behavior during stretching. The less ordered alpha form crystal of PLA can be formed in the
un-annealed PLA samples and those that were annealed at 70 oC with low crystallinity. The crystallinity
increases with increasing annealing temperature and a' form crystal is formed when the annealing
temperature is higher than 100 oC. The stretched samples with low crystallinity show the first yield at
draw temperatures below the glass transition temperature (Tg) and the second yield above Tg. For the
samples annealed between 80 and 120 oC, a peculiar double yield appears when stretched within
50–60 oC and only the first or the second yield can be found at the lower and higher draw
temperatures. The yield strain and yield stress together with Young's modulus were obtained and
discussed in terms of the effects of the draw temperature and crystalline structure of PLA samples.