Abstract
Owing to their huge specific surface area, high porosity, abundant metal active sites, adjustable structure, and tunable pore diameters, metal-organic frameworks (MOFs) have attracted much attention from the battery scientists and technologists. MOFs have proven to be versatile precursors of cathode materials for batteries, and MOF-based cathodes have already exhibited excellent electrochemical performances. Herein, we review some recent advances in developing MOF-derived cathodes for lithium-/sodium-ion batteries, lithium-sulfur batteries, lithium-air batteries, and lithium-selenium batteries. We also describe the synthetic mechanism, characterization of MOF-derived cathodes, and the origin of the enhanced electrochemical performances. Finally, we point out some challenges and opportunities for the future development of MOF-based cathodes.
Original language | English |
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Journal | ChemElectroChem |
Volume | 6 |
Issue number | 21 |
Pages (from-to) | 5358–5374 |
Number of pages | 17 |
ISSN | 2196-0216 |
DOIs | |
Publication status | Published - 31 Oct 2019 |
Keywords
- cathodes
- lithium-ion batteries
- lithium-sulfur batteries
- metal-organic frameworks
- sodium-ion batteries