TY - JOUR
T1 - Metal-Organic-Framework-Based Cathodes for Enhancing the Electrochemical Performances of Batteries
T2 - A Review
AU - Wang, Z.Y.
AU - Tao, H.Z.
AU - Yue, Yuanzheng
PY - 2019/10/31
Y1 - 2019/10/31
N2 - Owing to their huge specific surface area, high porosity, abundant metal active sites, adjustable structure, and tunable pore diameters, metal-organic frameworks (MOFs) have attracted much attention from the battery scientists and technologists. MOFs have proven to be versatile precursors of cathode materials for batteries, and MOF-based cathodes have already exhibited excellent electrochemical performances. Herein, we review some recent advances in developing MOF-derived cathodes for lithium-/sodium-ion batteries, lithium-sulfur batteries, lithium-air batteries, and lithium-selenium batteries. We also describe the synthetic mechanism, characterization of MOF-derived cathodes, and the origin of the enhanced electrochemical performances. Finally, we point out some challenges and opportunities for the future development of MOF-based cathodes.
AB - Owing to their huge specific surface area, high porosity, abundant metal active sites, adjustable structure, and tunable pore diameters, metal-organic frameworks (MOFs) have attracted much attention from the battery scientists and technologists. MOFs have proven to be versatile precursors of cathode materials for batteries, and MOF-based cathodes have already exhibited excellent electrochemical performances. Herein, we review some recent advances in developing MOF-derived cathodes for lithium-/sodium-ion batteries, lithium-sulfur batteries, lithium-air batteries, and lithium-selenium batteries. We also describe the synthetic mechanism, characterization of MOF-derived cathodes, and the origin of the enhanced electrochemical performances. Finally, we point out some challenges and opportunities for the future development of MOF-based cathodes.
KW - cathodes
KW - lithium-ion batteries
KW - lithium-sulfur batteries
KW - metal-organic frameworks
KW - sodium-ion batteries
UR - http://www.scopus.com/inward/record.url?scp=85071763814&partnerID=8YFLogxK
U2 - 10.1002/celc.201900843
DO - 10.1002/celc.201900843
M3 - Review article
SN - 2196-0216
VL - 6
SP - 5358
EP - 5374
JO - ChemElectroChem
JF - ChemElectroChem
IS - 21
ER -